I can't fit the room in one frame - this is the corner area, and to the right of the window pictured to the right is a deck in the other corner. The desks are now up against the wall, between the right [pictured] window and the corner, on each side. The rest of the room is just open.

Ok

You can put more than one photo in a post. Why not stand in the doorway and take two or three photos that overlap slightly. Then post them in left-to-right order.

I will go ahead and ask if you can set each desk so the occupant faces the center of the room? Most people feel better with a wall at their back and a view of the room's entry.

Maybe both desks facing each other.... moved toward the center of the room. You can create a privacy screen between the 2 desks with 2 back to back bookcases between the desks., if needed.

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Without power in the floor I haven't really pursued the central placement though do like the look

Sitting at a desk and looking at a wall wouldn't be my choice of a work space. Do you need 2 desks in the room? Usually a room of that size would be for one person/desk. Then you could have bookcases and file cabinets in the room as well. But if you need 2 desks, how about moving the chairs so that you face out into the room?

Adding to my comment above with 2 desks facing each other ..... I'm thinking if you place the desks as a grouping ... at an angle with the corner as in the pic, (creating a triangle) desks and walls corner ...between both windows, but moved toward center of the room, the space might work for you. You will have your backs to the other walls and not any windows. Kinda catty-corner to the room corner.

Catherine L, there are Cord Covers made for the floor that protect cords and prevent tripping. Using these you can run cords from an outlet to the desks, then use a surge connector power strip to plug in electronics. You do not have to have a plug in the middle of the floor to pull your desks away from the walls.