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HELP!! Did I just kill my tomatoes?? :(

've moved home in january and for the first time in my life I'm gardening! Yesterday somebody at work (I'm a physio) told me that it was going to rain in the evening I should spray my tomatoes with a solution of 1L water for 100g of baking soda and a few drops of soap to prevent mildium. I googled it and there were a lot of posts about this so I went for it. (It didn't rain after all). Today I came home and there are a lot black spots on the leafs, mostly on baby leafs... HELP ME, DID I JUST KILL MY TOMATOES?? What can I do to solve this? Should I try to clean the white powder that was left behind? I'm heartbroken! http://imgur.com/tAfA8aP

http://imgur.com/vzwzHp3

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