..."Should I split them in to two locations based on their needs?"...

Question you ask is the answer I would consider...

Great! Thank you! So should I put the ones which are not liking too much sunlight can be at location which will get sunlight from 2:00-7:00? That time is when the temps are at their highest. Just want to confirm.

It seems like that would be worth a shot, at least for a bit. If they still don't like that much heat, another solution will have to be found.

Some succulents do not like very strong and hot sunlight. I can't tell exactly what plants you have, but sort them out accordingly. For some, morning sunlight (sunrise to before noon) is very good. These would include Sans and Haworthias, and few more. If you have winter-growers, they will be likely best in more shade. Others will grow very well in your 2:00-7:00pm or all day sun. Make sure they are all well acclimatized to sun, or they can suffer sunburn.

If your weather is like it's been here in 6a (humid and 90-100 degrees), do NOT put them in the sun past 2 unless you like sunburned plants. I only have two that are okay outside with afternoon sun right now, a cactus and a crassula campfire. Everything else I had to move under cover by 2pm or sunburn city - including the sun worshipping PVNs.

Thank you all for your input. Yes, it has been very hot here ( west of Philly) and I think it going to get into 90’s over next few days. I am also leaning on keeping all the plants in one place and use a shade cloth for few hours a day. I can get a shade cloth but don’t have a structure to put that on. Thinking on how to do that? Any pictures or ideas? My setup is still under works... but posting a pic to see if you can give me suggestions on how to use shade cloth.

It would probably not win any awards in design/decoration category, but you could just drape it over when needed...I used to have one (and plastic sheet too, to protect plants from rain - but do not use them anymore, for few years). I stapled material to a long piece of wood (1x0.5" or similar). I attached this to a wall behind plants. You could attach it to railing. At the other end, I stapled it to another piece of wood/dowel, and whenever needed, I just rolled it up or down. If windy and it was rolled over plants, I just put few bricks on the bottom part to make sure it doesn't fly around (it was long enough for few inches to lay on the ground). You can have 2 pieces if distance is too long. Just an idea...

Perfect! For today I did this.. covered burlap that I had at home. Might have to order shade cloth online. I use tarp to protect them from heavy rain. Tarp works great but need to find a easy solution for sun protection as I need to do it more often.